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Novak Djokovic and Nick Kyrgios will face off for the first time since the Wimbledon final on Friday with tickets for the charity match selling out in 58 minutes.
Proceeds from the match at the Rod Laver Arena will go to the Australian Tennis Foundation.
The match will form part of both players' preparations for the Australian Open, which begins on Monday.
Djokovic is bidding to win a record 10th title in Melbourne.
Rafael Nadal, Daniil Medvedev, Coco Gauff, Maria Sakkari, Jessica Pegula, Stan Wawrinka, Dominic Thiem, Taylor Fritz, Alexander Zverev are among the other players involved in the warm-up matches this week before Friday's showdown between Djokovic and Kyrgios.